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Emulsion stabilization using polyelectrolytes : ウィキペディア英語版
Emulsion stabilization using polyelectrolytes
Polyelectrolytes are charged polymers capable of stabilizing (or destabilizing) colloidal emulsions through electrostatic interactions. Their effectiveness can be dependent on molecular weight, pH, solvent polarity, ionic strength, and the hydrophilic-lipophilic balance (HLB). Stabilized emulsions are useful in many industrial processes, including deflocculation, drug delivery, petroleum waste treatment, and food technology.
==Types of Polyelectrolytes==

Polyelectrolytes are made up of positively or negatively charged repeat units. The charge on a polyelectrolyte depends on the different properties of the solution, such as the degree of dissociation of the monomer units, the solvent properties, salt concentration, pH, and temperature.
Polymers become charged through the dissociation of the monomer side groups. If more monomer side groups are dissociated, the polymer has a higher charge. In turn, the charge of the polymer classifies the polyelectrolyte, which can be positive (cationic) or negative (anionic).
The polymer charge and ionic strength of the polyelectrolyte in question dictate how thick a polyelectrolyte layer will be. The thickness of a polyelectrolyte then affects its adsorption ability. For more information on polyelectrolyte adsorption, look here.
Some examples of polyelectrolytes can be found in the table below. The properties of the polymers vary with molecular weight and degree of polymerization.〔The molar masses and degree of polymerization reported are specific examples of polyelectrolytes synthesized and reported in various studies.〕

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